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Tectosilicate

SiO₄ tetrahedrons share all oxgens at corners each other and form 3 dimensional framework.

[SiO₂]⁰

SiO₂ is neutral by sharing all oxgens in SiO₄ tetrahedron. So, pure "tecto"silicate is oxide from strict point of view and it may not be able to form salt.

It can act as anion when a part of Si⁴⁺ is substituted by Al³⁺, B³⁺ and others.

• Tecto-borosilicate
• Tecto-aluminosilicate
• Tecto-Beryllium-silicate

[SiO2]

[SiO2] [Monoclinic C2/c]

Coesite

[SiO2] [Tetragonal P422]

Cristobalite

[SiO2] [Monoclinic I2/a]

Mogánite, Moganite

[SiO2] [Trigonal P321]

Quartz

[SiO2] [Hexagonal]

β-Quartz

[SiO2] [Triclinic F1]

Tridymite

Carbonate-Tecto-Aluminosilicate

[][A(3+)4][B(2+)2][(H2O)3|(CO3)4|Si8O20] [Tetragonal I4/mcm]

Miyawakiite-(Y)